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Kinetics of phase-transfer-catalyzed oxidations ofp-substituted benzyl alcohols with aqueous hypochlorite
(Springer Verlag, 1997)
A series ofp-substituted benzyl alcohols have been oxidized to their corresponding aldehydes using aqueous hypochlorite and phase-transfer catalyst (PTC) conditions. The reaction constant, p, has been determined to be ...
Metalation Reaction of 3,5-Dichloro-N-ethylbenzamide
(The College of New Jersey, 1999)
The metalation reaction of 3,5-dichloro-Nethylbenzamide was compared with that of 3,5-dichloro-N,N-diethylbenzamide in order to study the effects of regioselectivity and sterics of the functional groups. This is a ...
Epoxidation of Geraniol: An Advanced Organic Experiment that Illustrates Asymmetric Synthesis
(American Chemical Society, 1997)
The Sharpless epoxidation reaction is considered one of the most powerful advances in asymmetric organic synthesis (1). It is a classic example of the use of an asymmetric catalyst to provide an enantiomerically enriched ...
Metalation Reactions of 3,5-Dichloro-N,N-diethylbenzamide
(The College of New Jersey, 1998)
The competing influences of regiocontrol of the diethylamido and chloro functional groups were examined in the metalation reactions of 3,5-dichloro-N,N-diethylbenzamide. The compounds, 3,5-dichloro-4-methyl-N,Ndiethylbenzamide ...