• Login
    View Item 
    •   Digital Repository Home
    • TCNJ Scholars (Faculty and Student Research)
    • Faculty Research
    • Chemistry Department
    • View Item
    •   Digital Repository Home
    • TCNJ Scholars (Faculty and Student Research)
    • Faculty Research
    • Chemistry Department
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Ruthenium cluster compounds containing 1,1′-bis(diphenylphosphino)ferrocene (dppf): an electrochemical analysis and the crystal structure of [Ru3(CO)11]2(μ-dppf)

    Thumbnail
    Date
    8/1/2003
    Author
    O’Connor, Abby R.
    Nataro, Chip
    Rheingold, Arnold L.
    Metadata
    Show full item record
    Abstract
    Abstract
    The electrochemistry of 1,1′-bis(diphenylphosphino)ferrocene (dppf) derivatives of Ru3(CO)12 was investigated. Two known compounds [Ru3(CO)8(μ-dppf)2 (1) and Ru3(CO)10dppf (2)] and a new compound [Ru3(CO)11(μ-dppf)Ru3(CO)11 (3)] were prepared. Compound 3 was characterized spectroscopically and an X-ray crystal structure was obtained. The reductive electrochemistry of 1 and 2 showed an irreversible reduction and a follow-up oxidation, similar to Ru3(CO)12. The electrochemistry of compound 3 showed two irreversible waves and a follow-up oxidation. A trend in the reduction potential vs. the number of coordinated phosphorus atoms was noted. The oxidative electrochemistry of 1–3 showed a dppf-based chemically reversible wave, and an irreversible wave similar to that of Ru3(CO)12. Trends were also noted between the oxidation potential and the number of coordinated phosphorus atoms.
    Citation:
    O'Connor, A.R.; Nataro, C.; Rheingold, A.L., "Ruthenium cluster compounds containing 1,1′-bis(diphenylphosphino)ferrocene (dppf): an electrochemical analysis and the crystal structure of [Ru3(CO)11]2(μ-dppf)," Journal of Organometallic Chemistry, 2003, 679, 1, 72-78
    Description
    File not available for download due to copyright restrictions
    URI
    http://dx.doi.org/10.1016/S0022-328X(03)00512-6
    Collections
    • Chemistry Department

    DSpace software copyright © 2002-2016  DuraSpace
    | Send Feedback
    Theme by 
    Atmire NV
     

     

    Browse

    All of RepositoryCommunities & CollectionsBy Issue DateAuthorsTitlesSubjectsThis CollectionBy Issue DateAuthorsTitlesSubjects

    DSpace software copyright © 2002-2016  DuraSpace
    | Send Feedback
    Theme by 
    Atmire NV