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dc.contributor.authorO’Connor, Abby R.
dc.contributor.authorNataro, Chip
dc.contributor.authorRheingold, Arnold L.
dc.date.accessioned2015-06-24T15:27:22Z
dc.date.available2015-06-24T15:27:22Z
dc.date.issued8/1/2003
dc.identifier.citationO'Connor, A.R.; Nataro, C.; Rheingold, A.L., "Ruthenium cluster compounds containing 1,1′-bis(diphenylphosphino)ferrocene (dppf): an electrochemical analysis and the crystal structure of [Ru3(CO)11]2(μ-dppf)," Journal of Organometallic Chemistry, 2003, 679, 1, 72-78en_US
dc.identifier.urihttp://dx.doi.org/10.1016/S0022-328X(03)00512-6
dc.descriptionFile not available for download due to copyright restrictionsen_US
dc.description.abstractThe electrochemistry of 1,1′-bis(diphenylphosphino)ferrocene (dppf) derivatives of Ru3(CO)12 was investigated. Two known compounds [Ru3(CO)8(μ-dppf)2 (1) and Ru3(CO)10dppf (2)] and a new compound [Ru3(CO)11(μ-dppf)Ru3(CO)11 (3)] were prepared. Compound 3 was characterized spectroscopically and an X-ray crystal structure was obtained. The reductive electrochemistry of 1 and 2 showed an irreversible reduction and a follow-up oxidation, similar to Ru3(CO)12. The electrochemistry of compound 3 showed two irreversible waves and a follow-up oxidation. A trend in the reduction potential vs. the number of coordinated phosphorus atoms was noted. The oxidative electrochemistry of 1–3 showed a dppf-based chemically reversible wave, and an irreversible wave similar to that of Ru3(CO)12. Trends were also noted between the oxidation potential and the number of coordinated phosphorus atoms.en_US
dc.description.sponsorshipKresge Foundationen_US
dc.description.sponsorshipAmerican Chemical Society Petroleum Research Funden_US
dc.description.sponsorshipLafayette College, EXCEL scholarshipen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.subjectElectrochemistryen_US
dc.subject1,1'-bis(diphenylphosphino)ferroceneen_US
dc.subjectCrystal structureen_US
dc.subjectCyclic voltammetryen_US
dc.subjectSynthesisen_US
dc.titleRuthenium cluster compounds containing 1,1′-bis(diphenylphosphino)ferrocene (dppf): an electrochemical analysis and the crystal structure of [Ru3(CO)11]2(μ-dppf)en_US
dc.typeArticleen_US
dc.typeTexten_US
prism.publicationNameJournal of Organometallic Chemistryen_US
prism.volume679
prism.issueIdentifier1
prism.startingPage72
prism.endingPage78
dc.identifier.handlehttps://dr.tcnj.edu/handle/2900/86


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